During this arc, Zoro and Luffy, having lost their memories, confront each other and engage in a fight. It is during this fight that Zoro lands a strong surprise attack on Luffy, slicing his chest and thus giving him the X-shaped scar.
The arc is actually a loose adaption of a 2003 PlayStation game titled One Piece: Ocean's Dream! During this arc, Luffy and a hypnotized Zoro end up fighting, resulting in an X scar across Luffy's chest when he was wounded by Zoro.
SMH. Luffy got his scar on his chest from Roronoa Zoro this happened while Zoro's being controlled on Episode 223 from 10:55 - 11:10.
Luffy got his chest scar in episode 478 of One Piece anime titled “Akainu's Tenacity! The Fist of the Magma Attacks Luffy.” This episode corresponds with Chapter 578 of Volume 9 of the manga publication. There are, however, those that argue that Luffy got his chest scar in episode 223.
He got the scar from Akainu in Marineford. When Luffy fainted after Ace's death, Jinbei got him and wanted to escape. Akainu reached them and punched through Jinbei & Luffy in order to kill Luffy. Thanks to Jinbei, Luffy survived that, since he protected him from deadly injuries.
How did Zoro lose his left eye? He never lost it. It is a scar over his left eye that has been there after the time skip, and many fans are theorizing on what might have happened to it. For example, Zoro has a hidden power sealed beneath his left eye, and when he opens it, a hidden power is unleashed.
In the manga, it showed he lost it by throwing the little blade of Mihawk, like he did for the cursed sword, but he wasn't ready for even the tiny little knife and he loses his eye.
First off the scar is on his left eye. Zoro gained the scar after undergoing two years of training with Mihawk. It was at some point in between that 2 timeskip that Zoro obtained the scar over his left eye.
In the two-year time skip, Zoro trained under Dracule Mihawk, popularly known as Hawk Eyes Mihawk. One of the popular theories is that the scar on Zoro's left eye is a training mishap. Many believe that Zoro lost his left eye during his training in some sort of accident or battle.
In fact, I'm going to tell you exactly which episode of One Piece features Luffy getting his scar so you can NOT watch it. It happens in Marineford in episode 487 right after … Ace dies.
Technically speaking, Luffy doesn't have a gear technique called Gear 1. There is no mention of Gear 1 throughout the anime and manga. Thus, Luffy's base form, the usual rubbery body that he used in early episodes of the anime, can be considered “Gear 1.”
Shanks got his scar from Blackbeard the time he was with the Roger Pirates or before he created his own crew. At the meeting (ep. 434) with Whitebeard, Shanks said they have been fighting since then, means that Shanks got his scar before he became the captain of Red Hair Pirates.
That said, there is one crew member who stands above the rest in terms of loyalty to Luffy: Roronoa Zoro.
Luffy is the protagonist of the anime/manga series One Piece and the love interest of the pirate Empress Boa Hancock.
Many fans have speculated that it's due to a combination of his Armament Haki and rubber, with the former creating so much resistance as Luffy's arm stretches that it literally causes his fist and arm to ignite.
Regardless of how much stronger he was compared to the vast majority of the people he knew, deep down, he was aware of just far the gap was between him and his ultimate goal. This humbling affected Zoro on a deep level, so much so that it seems to have caused him to become much more serious.
He was asked to defeat the Humandrills on the island and, eventually, train with Mihawk as well. At some point, however, Zoro sustained an injury to his left eye. What exactly happened here remains unknown to date, however, Zoro's left eye has been closed ever since.
Roronoa Zoro learned how to imbue his swords with Armament Haki during the two-year timeskip when he trained under Mihawk. Thanks to his guidance, Zoro has become incredibly good at this skill.
He and Jimbei are currently the only known Seven Warlords who do not have Devil Fruit powers. The only duel between Shanks and Mihawk that was actually seen is in the game One Piece: Unlimited Cruise 2.
Prior to One Piece's timeskip, Zoro's left eye was fully functioning and completely uninjured. Yet when the Straw Hats reunited after their respective adventures, Zoro's left eye was mysteriously scarred shut.
Zoro is a very powerful fighter and he possesses all three types of Haki. Zoro was able to use Conqueror's Haki unknowingly against Kaido. Biggest Feat: With his newfound power, Zoro managed to defeat the right-hand man of Kaido. However, his biggest feat is scarring Kaido.
Enma is the strongest sword possessed by Zoro of the Straw Hat Pirates right now. What is Zoro's weakest sword? Sandai Kitetsu has to be the weakest sword Zoro has used until now in the One Piece manga and anime.
Over the years, he has come a long way and become one of the strongest pirates on the seas. Zoro has attained terrific strength, but he does not rely on a Devil Fruit at all.
Hito Hito no Mi, or human human fruit, is a zoan type devil fruit. This fruit's effects on humans are unnoticeable because the effect itself is turning the user into a human. If Sanji ate this fruit, the only ability he would gain is a swimming disability.